文献类型：期刊文献

英文题名：Formation of Soluble Furanic and Carbocyclic Oxy-Organics during the Hydrothermal Carbonization of Glucose

作者：Shi, Ning Liu, Qiying Liu, Ying Chen, Lijun Chen, Ni Peng, Jiayu Ma, Longlong

第一作者：Shi, Ning

通信作者：Shi, N[1];Shi, N[2];Shi, N[3]

机构：[1]Guizhou Inst Technol, Guiyang, Peoples R China;[2]Chinese Acad Sci, Guangzhou, Peoples R China;[3]Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou, Peoples R China

第一机构：贵州理工学院

通信机构：corresponding author), Guizhou Inst Technol, Guiyang, Peoples R China;corresponding author), Chinese Acad Sci, Guangzhou, Peoples R China;corresponding author), Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou, Peoples R China.|贵州理工学院;

年份：2020

卷号：34

期号：2

起止页码：1830-1840

外文期刊名：ENERGY & FUELS

收录：;EI(收录号：20200508107039);Scopus(收录号：2-s2.0-85078544999);WOS:【SCI-EXPANDED(收录号:WOS:000518215400073)】；

基金：This research received support from the High Level Scientific Research Funding Project of Guizhou Institute of Technology (0203001018036), the Academic New Seedling Plan Project of Guizhou Institute of Technology (Qian Ke He [20171578908), and the Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (no. Y909kr1001).

语种：英文

外文关键词：Carbonization - Condensation - Condensation reactions - Ketones - Liquid chromatography - Mass spectrometry - Thermochemistry

摘要：In this study, the water-soluble products formed during the hydrothermal carbonization of glucose were analyzed by liquid chromatography (LC)-mass spectrometry (MS) and LC-MS2 to determine the formulas and the possible structures of the main compounds. In addition to the well-known compounds of 3-deoxyglucosone, 5-hydroxymethylfurfural, and levulinic acid, the furanic compounds and the carbocyclic oxy-organics containing hydroxy group and carbonyl group with a molecular mass range between 170 and 260 Da were also identified. Both C-C coupling reaction and C-C cleavage reaction were proved to be involved during the formation of these carbocyclic oxy-organics, so they were proposed to be released via C-C cleavage of the primary polymers, which were formed by aldol condensation of the primary precursors formed during the degradation of glucose. The identification of these carbocyclic oxy-organics was indirect evidence that aldol condensation played a crucial role during the formation of hydrochar from carbonization of glucose.