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A Novel Yellow Phosphor(Ba3Sc2(BO3)4: Eu2+) Suitable for Full-Spectrum Lighting, Featuring Tunable Photoluminescence and Enhanced Luminous Thermal Stability  ( SCI-EXPANDED收录)  

文献类型:期刊文献

英文题名:A Novel Yellow Phosphor(Ba3Sc2(BO3)4: Eu2+) Suitable for Full-Spectrum Lighting, Featuring Tunable Photoluminescence and Enhanced Luminous Thermal Stability

作者:Liang, Pan Zhang, Hongshu Wang, Junfeng Xue, Yingyiing Li, Saying Li, Xin Wan, Ziyu Luo, Junxian Li, Lianqing Huang, Hongsheng Liu, Zhihong

第一作者:Liang, Pan

通信作者:Liang, P[1];Liu, ZH[2]

机构:[1]Shaanxi Xueqian Normal Univ, Sch Chem & Chem Engn, Xian 710100, Peoples R China;[2]Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China;[3]Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Peoples R China

第一机构:Shaanxi Xueqian Normal Univ, Sch Chem & Chem Engn, Xian 710100, Peoples R China

通信机构:corresponding author), Shaanxi Xueqian Normal Univ, Sch Chem & Chem Engn, Xian 710100, Peoples R China;corresponding author), Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Peoples R China.

年份:2025

外文期刊名:LASER & PHOTONICS REVIEWS

收录:;WOS:【SCI-EXPANDED(收录号:WOS:001487960100001)】;

基金:This work was supported by the National Natural Science Foundation of China (Grant No. 22003035, 21963006, 22073061), the Project of Shaanxi Province Youth Science and Technology New Star (2023KJXX-076), the National Training Program of Innovation and Entrepreneurship for Undergraduates (202314390018), and the Project of Shaanxi Xueqian Normal University Innovation Team.

语种:英文

外文关键词:Ba3Sc2(BO3)(4): Eu2+; full spectrum lighting; high color rendering index; thermal stability; tunable photoluminescence; yellow phosphor

摘要:Currently, the development of phosphors for full-spectrum lighting is a prominent research area in the field of illumination. In this study, a novel and highly efficient yellow phosphor (Ba3Sc2(BO3)(4): Eu2+, BSBO: Eu2+) is synthesized via the high-temperature solid-phase method for the first time. The excitation spectrum of this phosphor ranges from 225 to 480 nm, with a peak at 365 nm. The emission spectrum ranges from 450 to 720 nm, peaking at 555 nm, with a full width at half maximum (FWHM) of 113 nm. BSBO: Eu2+ shows outstanding quantum efficiencies (IQE = 94.3%, EQE = 33.3%). The emission spectrum and luminescent color can be tuned through cation substitution. The thermal stability of BSBO: Eu2+ is significantly enhanced by the partial replacement of Sc ions with smaller Al and Ga ions. To illustrate its practical application potential in full-spectrum lighting, BSBO: Eu2+ is combined with commercially available blue and red phosphors, resulting in a WLED warm light source with an outstanding color rendering index (Ra) of 94.4% and a correlated color temperature (CCT) of 3865 K. These results highlight the substantial potential of BSBO: Eu2+ in full-spectrum lighting applications.

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