文献类型：期刊文献

英文题名：Controlled fabrication of {101} and {001}-faceted Ti1(-x)Fe(x)O(2) nanoarchitectures with enhanced photocatalytic performance for degradation of pollutant antibiotics

作者：Wu, Yadong Ren, Xulin Zhu, Fusheng Li, Tao Zhang, Jianqiong Fu, Yuanxiang Zhang, Hongyan Feng, Xiaoqing Huang, Hongsheng Xie, Ruishi Hu, Wenyuan

通信作者：Huang, HS[1];Xie, RS[2];Hu, WY[2]|[144406c0812405d42e8a8]黄宏升;

机构：[1]Guizhou Inst Technol, Sch Int Educ, Sch Chem Engn, Guiyang 550003, Peoples R China;[2]Southwest Univ Sci & Technol, Sch Mat Sci & Engn, Analyt & Testing Ctr, Mianyang 621010, Peoples R China;[3]Guizhou Orthopaed Hosp, Guizhou Prov Peoples Hosp, Guiyang 550000, Peoples R China

第一机构：贵州理工学院化学工程学院

通信机构：corresponding author), Guizhou Inst Technol, Sch Int Educ, Sch Chem Engn, Guiyang 550003, Peoples R China;corresponding author), Southwest Univ Sci & Technol, Sch Mat Sci & Engn, Analyt & Testing Ctr, Mianyang 621010, Peoples R China.|贵州理工学院化学工程学院;贵州理工学院;

年份：2022

卷号：897

外文期刊名：JOURNAL OF ALLOYS AND COMPOUNDS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000749549900004)】；

基金：This study was supported by the Opening Foundation of Sichuan Province Engineering Research Center for Powder Metallurgy, Chengdu University (SC-FMYJ2020-01), High Level Talent Scientific Research Startup Project of Guizhou Institute of Technology (XJGC20190614), Fundamental Science on Nuclear Wastes and Environmental Safety Laboratory (19kfhk04), Key Laboratory of Energy Chemistry of Guizhou Province (No. Qian Jiao He Kyzi [2017] 009), and Science and Technology Project of Guizhou Province (No. Qian Ke He Ping Tai Ren Cai [2019] 5609), Application Foundation of Science and Technology Department of Sichuan Province (2020YJ0419) , and National Natural Science Foundation of China (2150344, 21963006 and 42072048).

语种：英文

外文关键词：Nanoarchitectures; Photocatalysis; Fe3+ -incorporation; Crystal plane; NAs-Ti1-xFexO2

摘要：Facing the increasing antibiotics pollution, it is essential to develop novel and highly efficient photocatalysts in purification systems. Herein, Fe3+-incorporated tetragonal bipyramid anatase TiO2 nanoarchitectures (NAs-Ti1-xFexO2) with exposure of highly active atoms (Fe, O and Ti) on the (101) and (001) surfaces were prepared via a hydrothermal process. Experimental studies show that these fabricated NAs-Ti1-xFexO2 exhibit excellent photocatalytic performance for degradation of pollutant antibiotics. Based on the stabilization mechanism, a detailed analysis of many active atoms were stabilized on the (101) and (001) surfaces of NAs-Ti1-xFexO2 due to Ti-O/Ti-F/Fe-F bond attractions. A series of characterization experiments show that Fe3+ is regarded as a significant component and participated in the reaction process for antibiotics degradation. Besides, high exposure of active atoms due to this Fe3+ incorporated tetragonal bipyramid anatase TiO2 (one dimensional sizes verge on 1-3 nm) further improves the separation efficiency of photogenerated carriers and free radical yield than traditional nanomaterials. What's more, the photoinduced electrons are also easier to transfer to the (101) crystal plane and the holes remained on the (001) crystal plane. In conclusion, excellent performance can be amplified, which is derived from smaller nanometric size. This study provides an insight into the enhanced photocatalytic degradation of pollutant antibiotics employing the Fe3+-incorporated tetragonal bipyramid anatase TiO2. (c) 2021 Elsevier B.V. All rights reserved.