文献类型：期刊文献

英文题名：Progress in Synthesis of Highly Active and Stable Nickel-Based Catalysts for Carbon Dioxide Reforming of Methane

作者：Kawi, Sibudjing Kathiraser, Yasotha Ni, Jun Oemar, Usman Li, Ziwei Saw, Eng Toon

第一作者：Kawi, Sibudjing

通信作者：Kawi, S[1]

机构：[1]Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore;[2]Zhejiang Univ Technol, Coll Chem Engn, Inst Ind Catalysis, Hangzhou 310014, Zhejiang, Peoples R China;[3]Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China

第一机构：Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore

通信机构：corresponding author), Natl Univ Singapore, Dept Chem & Biomol Engn, 4 Engn Dr 4, Singapore 117585, Singapore.

年份：2015

卷号：8

期号：21

起止页码：3556-3575

外文期刊名：CHEMSUSCHEM

收录：;EI(收录号：20154601536992);Scopus(收录号：2-s2.0-84946552074);WOS:【SCI-EXPANDED(收录号:WOS:000364525800004)】；

基金：We gratefully thank the National University of Singapore, a National Research Foundation grant (NRF-POC 001-055, RP No. 279-000-397-281), and a National Environmental Agency grant (NEA-ETRP 1002114, RP No. 279-000-333-490) for generously supporting this work. We sincerely thank Dr. W. Thitsartarn, Dr. T. Maneerung, Dr. K. Sutthiumporn, and M. L. Ang for their valuable help.

语种：英文

外文关键词：heterogeneous catalysis; nanoparticles; nickel; synthesis design; structure-activity relationships

摘要：In recent decades, rising anthropogenic greenhouse gas emissions (mainly CO2 and CH4) have increased alarm due to escalating effects of global warming. The dry carbon dioxide reforming of methane (DRM) reaction is a sustainable way to utilize these notorious greenhouse gases. This paper presents a review of recent progress in the development of nickel-based catalysts for the DRM reaction. The enviable low cost and wide availability of nickel compared with noble metals is the main reason for persistent research efforts in optimizing the synthesis of nickel-based catalysts. Important catalyst features for the rational design of a coke-resistant nickel-based nanocatalyst for the DRM reaction are also discussed. In addition, several innovative developments based on salient features for the stabilization of nickel nanocatalysts through various means (which include functionalization with precursors, synthesis by plasma treatment, stabilization/confinement on mesoporous/microporous/carbon supports, and the formation of metal oxides) are highlighted. The final part of this review covers major issues and proposed improvement strategies pertaining to the rational design of nickel-based catalysts with high activity and stability for the DRM reaction.