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Synthesis of Perfluoroalkyl-Substituted Oxindoles through Organophotoredox-Catalyzed Perfluoroalkylation of N -arylacrylamides with Perfluoroalkyl Iodides  ( SCI-EXPANDED收录)   被引量:19

文献类型:期刊文献

英文题名:Synthesis of Perfluoroalkyl-Substituted Oxindoles through Organophotoredox-Catalyzed Perfluoroalkylation of N -arylacrylamides with Perfluoroalkyl Iodides

作者:Yang, Zhiyong Tang, Anjiang

第一作者:杨志勇

通信作者:Yang, ZY[1]

机构:[1]Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China

第一机构:贵州理工学院化学工程学院

通信机构:corresponding author), Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China.|贵州理工学院化学工程学院;贵州理工学院;

年份:2019

卷号:30

期号:9

起止页码:1061-1066

外文期刊名:SYNLETT

收录:;WOS:【SCI-EXPANDED(收录号:WOS:000469034000011),CCR-EXPANDED(收录号:WOS:000469034000011)】;

基金:Joint Funds of the Department of Science of Guizhou Province for the Guizhou Institute of Technology, (Grant/Award Number: QKH20167093)

语种:英文

外文关键词:oxindoles; cyclization; perfluoroalkylation; photoredox reaction

摘要:An efficient process was developed for the perfluoroalkylation of N -arylacrylamides through an organocatalyzed photoredox/cyclization reaction of N -arylacrylamides with inexpensive perfluoroalkyl iodide reagents. The reaction employs an inexpensive organic dye, eosin Y, as the photoredox catalyst and is run under irradiation by a 26 W LED lightbulb.

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