文献类型：期刊文献

英文题名：Fluorescent brighteners in thiol-acrylate polymerizations: Sunlight-cured coatings and LED-assisted multifuctional intelligent nanoparticles synthesis

作者：Zuo, Xiao-ling Wu, Chong Yang, Le Huang, An-rong Dong, Ze-gang Wang, Teng-fei Xu, Fang Zhang, Dao-hai Guo, Jian-bing Yang, Yin-ye

第一作者：Zuo, Xiao-ling

通信作者：Zuo, XL[1];Yang, YY[1];Guo, JB[2]

机构：[1]Guizhou Minzu Univ, Coll Mat Sci & Engn, Guiyang 550025, Peoples R China;[2]Guizhou Minzu Univ, Coll Chem Engn, Guiyang 550025, Peoples R China;[3]Guizhou Univ Tradit Chinese Med, Coll Pharm, Guiyang 550025, Peoples R China;[4]Guizhou Inst Technol, Coll Mat Sci & Met Engn, Guiyang 550003, Peoples R China;[5]Natl Engn Res Ctr Compounding & Modificat Polymer, Guiyang 550014, Peoples R China

第一机构：Guizhou Minzu Univ, Coll Mat Sci & Engn, Guiyang 550025, Peoples R China

通信机构：corresponding author), Guizhou Minzu Univ, Coll Mat Sci & Engn, Guiyang 550025, Peoples R China;corresponding author), Natl Engn Res Ctr Compounding & Modificat Polymer, Guiyang 550014, Peoples R China.

年份：2020

卷号：148

外文期刊名：PROGRESS IN ORGANIC COATINGS

收录：;EI(收录号：20202508852018);Scopus(收录号：2-s2.0-85086586765);WOS:【SCI-EXPANDED(收录号:WOS:000573040000009)】；

基金：Xiao-ling Zuo is grateful for the financial supported by Science and Technology Fund of Guizhou Province, P. R. China (No. [2020]1Y209), Youth Science and Technology Talent Growth Project of Education Department of Guizhou Province, P. R. China (No. [2018]144) and Fund Project of Guizhou Minzu University, P. R. China (No. GZMU [2019]YB23). Chong Wu acknowledges the financial supported by Science and Technology Fund of Guizhou Province, P. R. China (No. 20191032).

语种：英文

外文关键词：Thiol-ene polymerization; Fluorescent brighteners; Visible-light LED; Coatings; Multifuctional intelligent nanoparticles

摘要：Fluorescent brighteners mediated, thiol-ene polymerizations retain the robustness of step-growth mechanism meanwhile introducing new features: biocompatible wavelengths of visible light and aqueous reaction conditions. The proposed visible-light thiol-ene polymerization of trithiol-triene monomer is shown to be an innovative, facile, and highly efficient route that constructs a versatile platform for synthesizing high-performance coatings and multifuctional intelligent nanoparticles, respectively performed in a bulk form and emulsion form. In particular, the achievement of the concept of natural-sunlight-triggered thiol-ene polymerization is extremely valuable for coating synthesis as the method is green and friendly to environment in a sustainable manner. Besides, the resulting poly(thioester) latexes are capable of being applicable as multi-stimuli-responsive nanocarriers sensitive to UV, pH and redox.