文献类型：期刊文献

中文题名：双硅型偶联剂的合成及防腐蚀性研究

英文题名：Synthesis and Corrosion Resistance of Bis-Silane Coupling Agent

作者：孙成军 邓莲丽 刘海峰 王柱

第一作者：孙成军

机构：[1]广州中国科学院工业技术研究院;[2]贵州理工学院化学工程学院

第一机构：广州中国科学院工业技术研究院,广州511458

年份：2017

卷号：31

期号：2

起止页码：76-81

中文期刊名：有机硅材料

外文期刊名：Silicone Material

收录：CSTPCD

基金：贵州省联合基金(黔科合LH字[2014]7368号);贵州省教育厅优秀人才奖励计划(黔教合KY字[2014]245);2015年度南沙区科技计划资助项目(2015KF026)

语种：中文

中文关键词：双硅型;硅烷偶联剂;双酚A双烯丙基醚;点击化学;盐雾试验

外文关键词：bis-silane, silane coupling agent, bisphenol A bisallyl ether, click chemistry, salt spray test

摘要：以巯丙基三甲氧基硅烷(MPS)、双酚A双烯丙基醚(BBA)为原料,通过巯基-烯烃点击反应,生成双硅型硅烷偶联剂(BSC,产率95%)。红外(FTIR)分析表明,反应后原料的双键伸缩振动吸收峰v_(C=C)、v=(C—H)、v_(S—H)均消失,说明发生了反应;核磁分析(~1H NMR)表明产物结构为目标产物BSC。将BSC配制成水解液后加热固化成膜,采用热重分析仪(TGA)、极化曲线法(PCA)、盐雾腐蚀试验(SPT)等方法分析膜层的热稳定性、耐腐蚀等性能。结果表明,BSC膜层热稳定性能优于MPS水解液膜层;极化电阻为17 833Ω/cm^2,腐蚀速率为1.18×10^(-2)mm/a;盐雾加速腐蚀实验表明,BSC的防护性能明显优于MPS;BSC膜层耐冲击性能大于100 cm·kg,耐弯曲性能1级,附着力0级,硬度2H。
A bi-silane coupling agent （BSC） was synthesized with the yield of 95% by reacting 3-mercap- topropyhrimethoxysilane （MPS） with bisphenol A bisallyl ether （BBA）. It was proved that BBA reacted with MPS because of the disappearance of the stretching vibration absorption of v c=c ,V=C-H ,VS-H via FFIR. The chemical structure of the compound （BSC） was characterized by 1H NMR. The thermo-stability and corrosion resistance of the cured BSC hydrolysate film were characterized by thermo-gravimetric analysis （TGA）, polari- zation curve analysis （PCA） and the salt spray test （SPT）, respectively. Thermo-gravimetric analysis shows that the cured BSC hydrolysate film has better thermo-stability than that of MPS. The polarization resistance of the film is 178331Ω/cm^2 and its corrosion rate is 1.18 ×10^-2mm/a by polarization curve analysis. The salt spray test shows that the cured BSC hydrolysate film has more prominent corrosion resistance than that of MPS. The cured BSC hydrolysate film on iron sheet withstands more than 100 cm ~ kg impact and bending level 1. Moreover, its adhesion and hardness grade are 0 and 2H, respectively.