详细信息
Glycerol Cu(II) Complex Supported on Fe3O4 Magnetic Nanoparticles: A New and Highly Efficient Reusable Catalyst for the Formation of Aryl-Sulfur and Aryl-Oxygen Bonds ( SCI-EXPANDED收录) 被引量:27
文献类型:期刊文献
英文题名:Glycerol Cu(II) Complex Supported on Fe3O4 Magnetic Nanoparticles: A New and Highly Efficient Reusable Catalyst for the Formation of Aryl-Sulfur and Aryl-Oxygen Bonds
作者:Ashraf, Muhammad Ageel Liu, Zhenling Peng, Wan-Xi Zhou, Liang
第一作者:Ashraf, Muhammad Ageel
通信作者:Peng, WX[1];Zhou, L[2]
机构:[1]Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Henan, Peoples R China;[2]Univ Malaya, Fac Sci, Dept Geol, Kuala Lumpur 50603, Malaysia;[3]Henan Univ Technol, Sch Management, Zhengzhou 450001, Henan, Peoples R China;[4]Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China
第一机构:Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Henan, Peoples R China
通信机构:corresponding author), Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Henan, Peoples R China;corresponding author), Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China.|贵州理工学院化学工程学院;贵州理工学院;
年份:2020
卷号:150
期号:4
起止页码:1128-1141
外文期刊名:CATALYSIS LETTERS
收录:;WOS:【SCI-EXPANDED(收录号:WOS:000490235700002),CCR-EXPANDED(收录号:WOS:000490235700002)】;
语种:英文
外文关键词:C-O coupling; C-S coupling; Cu; Fe3O4@SiO2-Glycerol-Cu(II); Heterogeneous catalyst
摘要:In the present study, copper complex supported on surface-modified Fe3O4/SiO2 nanoparticles (Fe3O4@SiO2-Glycerole-Cu(II)) was successfully fabricated and characterized by fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray mapping, energy-dispersive X-ray spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), N-2 adsorption and desorption (BET) and Vibrating Sample Magnetometer (VSM) techniques. This magnetic nanocatalyst utilized as an effective catalyst for the C-S and C-O cross-coupling reactions of aryl halides with thiourea and phenol. The catalyst could be quickly and completely recovered using an external magnetic field and reused for six reaction cycles without significant change in catalytic activity. [GRAPHICS] .
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