文献类型：期刊文献

中文题名：酱香型白酒中金属元素的分析研究

英文题名：Analysis of mental elements in Moutai-flavor Baijiu

作者：谢小林 江伟 吴德光

第一作者：谢小林

机构：[1]贵州理工学院食品药品制造工程学院;[2]贵州茅台酒厂责任有限公司;[3]茅台学院

第一机构：贵州理工学院食品药品制造工程学院

年份：2017

卷号：36

期号：11

起止页码：158-160

中文期刊名：中国酿造

外文期刊名：China Brewing

收录：CSTPCD;;北大核心:【北大核心2014】；

基金：贵州省科技联合基金(黔科合LH字[2016]7091);贵州省省市科技合作专项资金项目(省市科合[2014]06号)

语种：中文

中文关键词：电感耦合等离子体发射光谱法;电感耦合等离子体质谱法;酱香型白酒;金属元素;检测

外文关键词：ICP-OES;ICP-MS;Moutai-flavour Baijiu;mental elements;determination

摘要：采用电感耦合等离子体光度发射光谱法(ICP-OES)和电感耦合等离子体质谱法(ICP-MS)测定酱香型白酒中的常量金属元素、重金属元素及稀土元素。结果表明,茅河酒中铝(Al)、钡(Ba)、锌(Zn)、镍(Ni)、铈(Ce)含量相对较高,分别为17.37 mg/L、19.20μg/L、21.41μg/L、27.25μg/L、2.72μg/L;茅渡酒中钙(Ca)、钡(Ba)、锌(Zn)、锶(Sr)、铈(Ce)含量相对较高,分别为12.21 mg/L、12.30μg/L、53.03μg/L、14.37μg/L、2.01μg/L;两种酒中均未检测出铕(Eu)、铽(Tb)。回收率实验结果表明,常量金属元素回收率为96.91%~107.80%,相对标准偏差(RSD)为2.1%~2.9%;重金属元素回收率为80.0%~109.0%,RSD为2.3%~3.9%。表明ICP-OES和ICP-MS法准确度高,采用该方法测定白酒中的金属元素是可行的。
The constant metal elements, heavy metal elements and rare earth elements in Moutai-flavour Baijiu(Chinese liquor) were determined by inductively coupled plasma-optical emission spectrometry(ICP-OES) and inductively coupled plasma-mass spectrometry(ICP-MS). The determination results showed that the contents of Al, Ba, Zn, Ni, Ce in Maohe Baijiu were relatively high, which were 17.37 mg/L, 19.20 μg/L, 21.41 μg/L,27.25 μg/L and 2.72 μg/L, respectively. The contents of Ca, Ba, Zn, Sr and Ce in Maodu Baijiu were relatively high, which were 12.21 mg/L, 12.30 μg/L,53.03 μg/L, 14.37 μg/L and 2.01 μg/L, respectively. Eu and Tb in two kinds of Baijiu were not detected. The results of recovery rate experiments showed that the recovery rate of constant metal elements were 96.91%-107.80%, the relative standard deviation(RSD) were 2.1%-2.9%; the recovery rate of heavy metal elements was 80.0%-109.0%, and the RSD was 2.3%-3.9%, which indicated that the ICP-OES and ICP-MS method was with high accuracy degree. So it was feasible to determine the metal elements in Baijiu.