文献类型：期刊文献

英文题名：Novel Intumescent Flame Retardant Masterbatch Prepared through Different Processes and Its Application in EPDM/PP Thermoplastic Elastomer: Thermal Stability, Flame Retardancy, and Mechanical Properties

作者：He, Weidi Zhou, Ying Chen, Xiaolang Guo, Jianbing Zhou, Dengfeng Chen, Shaopeng Wang, Meng Li, Lingtong

第一作者：He, Weidi

通信作者：Chen, XL[1];Guo, JB[1];Chen, XL[2]

机构：[1]Natl Engn Res Ctr Compounding & Modificat Polymer, Guiyang 550014, Guizhou, Peoples R China;[2]Southwest Jiaotong Univ, Sch Mat Sci & Engn, Key Lab Adv Mat Technol, Minist Educ, Chengdu 610031, Sichuan, Peoples R China;[3]Guizhou Inst Technol, Special Funct Mat Collaborat Innovat Ctr Guizhou, Guiyang 550003, Guizhou, Peoples R China;[4]Guizhou Inst Technol, Key Lab Light Met Mat Proc Technol Guizhou Prov, Guiyang 550003, Peoples R China

第一机构：Natl Engn Res Ctr Compounding & Modificat Polymer, Guiyang 550014, Guizhou, Peoples R China

通信机构：corresponding author), Natl Engn Res Ctr Compounding & Modificat Polymer, Guiyang 550014, Guizhou, Peoples R China;corresponding author), Southwest Jiaotong Univ, Sch Mat Sci & Engn, Key Lab Adv Mat Technol, Minist Educ, Chengdu 610031, Sichuan, Peoples R China.

年份：2019

卷号：11

期号：1

外文期刊名：POLYMERS

收录：;EI(收录号：20190206353283);Scopus(收录号：2-s2.0-85059517637);WOS:【SCI-EXPANDED(收录号:WOS:000457202000050)】；

基金：This work is financially supported by National Natural Science Foundation of China (51602067), Program of Application and Industrialization of Scientific and Technological Achievements of Guizhou (2016-4538), High-level Innovative Talents Training Project of Guizhou (2016/5667), International Science and Technology Cooperation Project of Chengdu (2017-GH02-00051-HZ), Science and Technology Funds of Baiyun District of Guiyang (2017/66, 2018/10) and Science and Technology Foundation of Guizhou (2018/1087).

语种：英文

外文关键词：ethylene-propylene-diene monomer; polypropylene; reactive extruding; intumescent flame retardant

摘要：In this work, the ethylene-propylene-diene monomer/polypropylene (EPDM/PP) thermoplastic elastomer filled with intumescent flame retardants (IFR) is fabricated by melting blend. The IFR are constituted with melamine phosphate-pentaerythritol (MP/PER) by compounding and reactive extruding, respectively. The effects of two kinds of MP/PER with different contents on the thermal stability, flame retardancy, and mechanical properties of materials are investigated by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL-94, cone calorimeter test (CCT), and scanning electron microscopy (SEM). FTIR results show that the reactive extruded MP/PER partly generates melamine pyrophosphate (MPP) compared with compound masterbatches. TGA data indicate that the best thermal stability is achieved when the molar ratio of MP/PER reaches 1.8. All the reactive samples show a higher flame retardancy than compound ones. The CCT results also exhibit the same trend as above in heat release and smoke production rate. The EPDM/PP composites filled with 30 and 35% reactive MP/PER exhibit the improved flame retardancy but become stiffer and more brittle. SEM photos display that better dispersion and smaller particle size are obtained for reactive samples.