文献类型：期刊文献

英文题名：Effects of Poly(butyleneadipate-co-terephthalate) as a Macromolecular Nucleating Agent on the Crystallization and Foaming Behavior of Biodegradable Poly(lactic acid)

作者：Liu, Wei Chen, Peng Wang, Xiangdong Wang, Fuchun Wu, Yujiao

第一作者：Liu, Wei

通信作者：Liu, W[1]|[14440e1cfacde39bad4ab]刘伟;

机构：[1]Guizhou Inst Technol, Sch Mat & Met Engn, Guiyang 550001, Guizhou, Peoples R China;[2]Beijing Technol & Business Univ, Sch Mat & Mech Engn, Beijing 100048, Peoples R China

第一机构：贵州理工学院材料与冶金工程学院

通信机构：corresponding author), Guizhou Inst Technol, Sch Mat & Met Engn, Guiyang 550001, Guizhou, Peoples R China.|贵州理工学院材料与冶金工程学院;贵州理工学院;

年份：2017

卷号：36

期号：2

起止页码：75-96

外文期刊名：CELLULAR POLYMERS

收录：;EI(收录号：20171503550153);Scopus(收录号：2-s2.0-85016759512);WOS:【SCI-EXPANDED(收录号:WOS:000408479900002)】；

基金：This work was supported by the Joint Research Program of the Science and Technology Department of Guizhou Province (Grant No. QianKeHe LH [2014] 7372), Research Program of Talented Scholars of Guizhou Institute of Technology (Grant No. XJG20141103), and the National Natural Science Foundation of China (Grant No. 51504073).

语种：英文

外文关键词：Macromolecular nucleating agent; Poly(lactic acid); Poly(butyleneadipate terephthalate); Foaming materials; Crystallization kinetics

摘要：The effect of a bio-based macromolecule, poly(butylene adipate-co-terephthalate) (PBAT), on the crystallization and foaming behavior of poly(lactic acid) (PLA) was evaluated. The crystallization kinetics results show that the addition of PBAT improved the crystallization of PLA by increasing the overall crystallinity and enhancing the crystal morphology of PLA. The massive crystallization zones may have prevented the escape of foaming gases to the surrounding area; the expansion ratio of the PLA foams increased from 4.87 to 10.94. Thus, a novel macromolecular crystallization nucleating agent for PLA was developed; the effect of the crystallization of PLA on its foaming behavior was also investigated. A high expansion ratio and finer cellular structure of PLA foam were obtained by optimizing the PBAT content.