文献类型：期刊文献

中文题名：Effect of Preparation Method on the Structural Characteristics of NiO-ZrO2 Oxygen Carriers for Chemical-looping Combustion

英文题名：Effect of Preparation Method on the Structural Characteristics of NiO-ZrO2 Oxygen Carriers for Chemical-looping Combustion

作者：Liu Yike Long Yanhui Tang Yaqin Gu Zhenhua Li Kongzhai

第一作者：LIU Yike;刘仪柯

通信作者：Gu, ZH[1];Gu, ZH[2];Gu, ZH[3]

机构：[1]Guizhou Inst Technol, Sch Mat & Met Engn, Guiyang 550003, Guizhou, Peoples R China;[2]Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Yunnan, Peoples R China;[3]Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Yunnan, Peoples R China;[4]Kunming Univ Sci & Technol, Minist Educ, Engn Res Ctr Met Energy Conservat & Emiss Reduct, Kunming 650093, Yunnan, Peoples R China

第一机构：贵州理工学院材料与冶金工程学院

通信机构：corresponding author), Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Yunnan, Peoples R China;corresponding author), Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Yunnan, Peoples R China;corresponding author), Kunming Univ Sci & Technol, Minist Educ, Engn Res Ctr Met Energy Conservat & Emiss Reduct, Kunming 650093, Yunnan, Peoples R China.

年份：2019

卷号：35

期号：6

起止页码：1024-1031

中文期刊名：高等学校化学研究：英文版

外文期刊名：CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

收录：CSTPCD;;Scopus;CSCD:【CSCD2019_2020】；

基金：Supported by the National Natural Science Foundation of China(No.51604137) and the Natural Science Foundation of Guizhou Province, China(No.QianKeHe[2017]1064).

语种：英文

中文关键词：Chemicalooping;combustion;NiO-ZrO2;oxygen;carrier;Solution;combustion;method;Mechanical;mixing;method;Coprecipitation;method

外文关键词：Chemical-looping combustion; NiO-ZrO2 oxygen carrier; Solution combustion method; Mechanical mixing method; Coprecipitation method

摘要：Chemical-looping combustion(CLC)offers an effective approach for power generation and CO2 capture.In this work,an NiO-ZrO2 oxygen carrier prepared by three methods was subjected to an optimal reaction temperature test,an optimal flow test and a cyclic redox reaction test to explore the most suitable reaction conditions.Through comparative analysis,it is noted that the coprecipitation method is not suitable for the preparation of this NiO-ZrO2 oxygen carrier,while the oxygen carrier prepared by the mechanical mixing method and solution combustion method obtained a higher CH4 conversion rate and CO2 selectivity.In addition,these two oxygen carriers also showed high stability during successive CLC testing.Therefore,both the mechanical mixing method and the solution combustion method can be used to prepare NiO-ZrO2 oxygen carriers.
Chemical-looping combustion(CLC) offers an effective approach for power generation and CO2 capture. In this work, an NiO-ZrO2 oxygen carrier prepared by three methods was subjected to an optimal reaction temperature test, an optimal flow test and a cyclic redox reaction test to explore the most suitable reaction conditions. Through comparative analysis, it is noted that the coprecipitation method is not suitable for the preparation of this NiO-ZrO2 oxygen carrier, while the oxygen carrier prepared by the mechanical mixing method and solution combustion method obtained a higher CH4 conversion rate and CO2 selectivity. In addition, these two oxygen carriers also showed high stability during successive CLC testing. Therefore, both the mechanical mixing method and the solution combustion method can be used to prepare NiO-ZrO2 oxygen carriers.